1994-2002 [Subscribe to Daily Digest] |
This is the safety sheet for these products, which seem do describe group III oils. Look for:
"This product contains synthetic base oils not refined from petroleum base stocks." and other references to "hydrocracked"
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Havoline® Synthetic Motor Oil
MSDS: 8602 Revision #: 1 Revision Date: 02/06/02
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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TEXACO Havoline Synthetic Motor Oil
PRODUCT NUMBER(S): CPS222100 CPS222101 CPS222102
SYNONYM: TEXACO Havoline Synthetic Motor Oil SAE 10W-30
TEXACO Havoline Synthetic Motor Oil SAE 5W-30
TEXACO Havoline Synthetic Motor Oil SAE 5W-40
COMPANY IDENTIFICATION EMERGENCY TELEPHONE NUMBERS
ChevronTexaco Global Lubricants HEALTH (24 hr): (800)231-0623 or
6001 Bollinger Canyon Road (510)231-0623 (International)
San Ramon, CA 94583 TRANSPORTATION (24 hr): CHEMTREC
(800)424-9300 or (703)527-3887
Emergency Information Centers
are located in U.S.A.
Int'l collect calls accepted
PRODUCT INFORMATION: MSDS Request: (800) 414-6737
Product Information: (800) LUBE-TEK
Email: lubemsds@chevrontexaco.com
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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100.0 % TEXACO Havoline Synthetic Motor Oil
CONTAINING
COMPONENTS AMOUNT LIMIT/QTY AGENCY/TYPE
HYDROTREATED DIST., HVY PARA
Chemical Name: DISTILLATES, HYDROTREATED HEAVY PARAFFINIC
CAS64742547 > 80.00% 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5 mg/m3 (mist) OSHA PEL
AND
SOLVENT DEWAXED DIST., HVY PAR
Chemical Name: DISTILLATES, SOLVENT DEWAXED HEAVY PARAFFINIC
CAS64742650 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5 mg/m3 (mist) OSHA PEL
ADDITIVES INCLUDING THE FOLLOWING
< 20.00%
ZINC ALKYL DITHIOPHOSPHATE
Chemical Name: PHOSPHORODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALT
CAS68649423 < 5.00% NONE NA
COMPOSITION COMMENT:
All the components of this material are on the Toxic Substances Control
Act Chemical Substances Inventory.
This product fits the ACGIH definition for mineral oil mist. The ACGIH
TLV is 5 mg/m3, the OSHA PEL is 5 mg/m3.
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3. HAZARDS IDENTIFICATION
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IMMEDIATE HEALTH EFFECTS
EYE:
Not expected to cause prolonged or significant eye irritation.
SKIN:
Contact with the skin is not expected to cause prolonged or significant
irritation. Not expected to be harmful to internal organs if absorbed
through the skin.
INGESTION:
Not expected to be harmful if swallowed.
INHALATION:
Contains a synthetic hydrocarbon base oil. May cause respiratory
irritation or other pulmonary effects following prolonged or repeated
inhalation of oil mist at airborne levels above the recommended mineral
oil mist exposure limit.
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4. FIRST AID MEASURES
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EYE:
No specific first aid measures are required because this material is not
expected to cause eye irritation. As a precaution remove contact lenses,
if worn, and flush eyes with water.
SKIN:
No specific first aid measures are required because this material is not
expected to be harmful if it contacts the skin. As a precaution, remove
clothing and shoes if contaminated. Wash skin with soap and water. Wash
or clean contaminated clothing and shoes before reuse.
INGESTION:
No specific first aid measures are required because this material is not
expected to be harmful if swallowed. Do not induce vomiting. As a
precaution, give the person a glass of water or milk to drink and get
medical advice. Never give anything by mouth to an unconscious person.
INHALATION:
If exposed to excessive levels of material in the air, move the exposed
person to fresh air. Get medical attention if coughing or respiratory
discomfort occurs.
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5. FIRE FIGHTING MEASURES
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FIRE CLASSIFICATION:
Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or
combustible.
FLAMMABLE PROPERTIES:
FLASH POINT: COC 440F (227C) Min.
AUTOIGNITION: NDA
FLAMMABILITY LIMITS (% by volume in air): Lower: NA Upper: NA
EXTINGUISHING MEDIA:
CO2, Dry Chemical, Foam, Water Fog
NFPA RATINGS: Health 1; Flammability 1; Reactivity 0.
FIRE FIGHTING INSTRUCTIONS:
This material will burn although it is not easily ignited. For fires
involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing
apparatus.
COMBUSTION PRODUCTS:
Normal combustion forms carbon dioxide and water vapor and may produce
oxides of Ca, S, and Zn. Heating this material may produce H2S.
Incomplete combustion can produce carbon monoxide.
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6. ACCIDENTAL RELEASE MEASURES
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CHEMTREC EMERGENCY NUMBER (24 hr): (800)424-9300 or (703)527-3887
International Collect Calls Accepted
ACCIDENTAL RELEASE MEASURES:
Stop the source of the leak or release. Clean up releases as soon as
possible, observing precautions in Exposure Controls/Personal Protection.
Contain liquid to prevent further contamination of soil, surface water or
groundwater. Clean up small spills using appropriate techniques such as
sorbent materials or pumping. Where feasible and appropriate, remove
contaminated soil. Follow prescribed procedures for reporting and
responding to larger releases.
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7. HANDLING AND STORAGE
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Container is not designed to contain pressure. Do not use pressure to
empty container or it may rupture with explosive force. Empty containers
retain product residue (solid, liquid, and/or vapor) and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such
containers to heat, flame, sparks, static electricity, or other sources of
ignition. They may explode and cause injury or death. Empty containers
should be completely drained, properly closed, and promptly returned to a
drum reconditioner, or properly disposed of. Avoid contaminating soil or
releasing this material into sewage and drainage systems and bodies of
water.
______________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
______________________________________________________________________
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3),
applicable exposure limits, job activities, and other substances in the
work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not
adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the
equipment since protection is usually provided for a limited time or under
certain circumstances.
Special Note: Do not use in breathing air apparatus or medical equipment.
ENGINEERING CONTROLS
Use in a well-ventilated area. If user operations generate an oil mist,
use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below the recommended mineral oil mist
exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION:
No special eye protection is normally required. Where splashing is
possible, wear safety glasses with side shields as a good safety practice.
SKIN PROTECTION:
No special protective clothing is normally required. Where splashing is
possible, select protective clothing depending on operations conducted,
physical requirements and other substances. Suggested materials for
protective gloves include: <Viton> <Nitrile> <Silver Shield>
RESPIRATORY PROTECTION:
No respiratory protection is normally required. If user operations
generate an oil mist, determine if airborne concentrations are below the
recommended mineral oil mist exposure limits. If not wear a NIOSH approved
respirator that provides adequate protection from measured concentrations
of this material. Use the following elements for air-purifying
respirators: particulate.
______________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
______________________________________________________________________
PHYSICAL DESCRIPTION:
Amber liquid.
pH: NA
VAPOR PRESSURE: <0.01 mm Hg at 100F
VAPOR DENSITY
(AIR=1): Heavier than air.
BOILING POINT: >425F (>218C)
FREEZING POINT: NA
MELTING POINT: NA
SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water.
SPECIFIC GRAVITY: 0.86 15.6/15.6C
VISCOSITY: 10.0 - 17.4 cSt @ 100C (Min.)
______________________________________________________________________
10. STABILITY AND REACTIVITY
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HAZARDOUS DECOMPOSITION PRODUCTS:
H2S may be released at high temperatures.
CHEMICAL STABILITY:
Stable.
CONDITIONS TO AVOID:
No data available.
INCOMPATIBILITY WITH OTHER MATERIALS:
May react with strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc.
HAZARDOUS POLYMERIZATION:
Polymerization will not occur.
______________________________________________________________________
11. TOXICOLOGICAL INFORMATION
______________________________________________________________________
EYE EFFECTS:
The eye irritation hazard is based on data for a similar material.
SKIN EFFECTS:
The skin irritation hazard is based on data for a similar material.
ACUTE ORAL EFFECTS:
The acute oral toxicity is based on data for a similar material.
ACUTE INHALATION EFFECTS:
The acute respiratory toxicity is based on data for a similar material.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains synthetic base oils not refined from petroleum base
stocks. The potential of base oil prepared by this process to cause
cancer has not been specifically addressed by the OSHA Hazard
Communication Standard (29 CFR 1910.1200), the International Agency for
Research on Cancer (IARC), nor the National Toxicology Program (NTP)
Annual Report. However, the process conditions, chemical analysis, and
the results of mutagenicity tests all support our opinion that these oils
should not cause skin cancer.
This product contains zinc alkyl dithiophosphates (ZDDPs). Several ZDDPs
have been reported to have weak mutagenic activity in cultured mammalian
cells but only at concentrations that were toxic to the test cells. We do
not believe that there is any mutagenic risk to workers exposed to ZDDPs.
During use in engines, contamination of oil with low levels of
cancer-causing combustion products occurs. Used motor oils have been
shown to cause skin cancer in mice following repeated application and
continuous exposure. Brief or intermittent skin contact with used motor
oil is not expected to have serious effects in humans if the oil is
thoroughly removed by washing with soap and water.
______________________________________________________________________
12. ECOLOGICAL INFORMATION
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ECOTOXICITY:
The toxicity of this material to aquatic organisms has not been evaluated.
Consequently, this material should be kept out of sewage and drainage
systems and all bodies of water.
ENVIRONMENTAL FATE:
This material is not expected to be readily biodegradable.
______________________________________________________________________
13. DISPOSAL CONSIDERATIONS
______________________________________________________________________
Oil collection services and collection centers are available for used
motor oil recycling or disposal. Some service stations, automotive
service centers, and retailers provide motor oil collection facilities.
Place contaminated materials in containers and dispose of in a manner
consistent with applicable regulations. Contact your sales representative
or local environmental or health authorities for approved disposal or
recycling methods.
______________________________________________________________________
14. TRANSPORT INFORMATION
______________________________________________________________________
The description shown may not apply to all shipping situations.
Consult 49CFR, or appropriate Dangerous Goods Regulations, for
additional description requirements (e.g., technical name) and
mode-specific or quantity-specific shipping requirements.
DOT SHIPPING NAME: NONE
DOT HAZARD CLASS: NONE
DOT IDENTIFICATION NUMBER: NONE
DOT PACKING GROUP: N/A
ADDITIONAL INFO: Lubricating Oil, N.O.I.B.N. - Not hazardous by U.S.DOT.
ADR/RID Hazard Class - Not applicable
______________________________________________________________________
15. REGULATORY INFORMATION
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SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects: NO
2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO
REGULATORY LISTS SEARCHED:
01=SARA 313 11=NJ RTK 22=TSCA Sect 5(a)(2)
02=MASS RTK 12=CERCLA 302.4 23=TSCA Sect 6
03=NTP Carcinogen 13=MN RTK 24=TSCA Sect 12(b)
04=CA Prop 65-Carcin 14=ACGIH TWA 25=TSCA Sect 8(a)
05=CA Prop 65-Repro Tox 15=ACGIH STEL 26=TSCA Sect 8(d)
06=IARC Group 1 16=ACGIH Calc TLV 27=TSCA Sect 4(a)
07=IARC Group 2A 17=OSHA PEL 28=Canadian WHMIS
08=IARC Group 2B 18=DOT Marine Pollutant 29=OSHA CEILING
09=SARA 302/304 19=Chevron TWA 30=Chevron STEL
10=PA RTK 20=EPA Carcinogen 31=OSHA STEL
The following components of this material are found on the regulatory
lists indicated.
DISTILLATES, HYDROTREATED HEAVY PARAFFINIC
is found on lists: 14,15,17,
DISTILLATES, SOLVENT DEWAXED HEAVY PARAFFINIC
is found on lists: 14,15,17,
PHOSPHORODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
is found on lists: 01,11,
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A.
34:5A-1 et. seq., the product is to be identified as follows:
PETROLEUM OIL
WHMIS CLASSIFICATION:
This product is not considered a controlled product according to the
criteria of the Canadian Controlled Products Regulations.
______________________________________________________________________
16. OTHER INFORMATION
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NFPA RATINGS: Health 1; Flammability 1; Reactivity 0;
HMIS RATINGS: Health 1; Flammability 1; Reactivity 0;
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal
Protection Equipment Index recommendation, *- Chronic Effect
Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection
Association (NFPA) or the National Paint and Coating Association
(for HMIS ratings).
REVISION STATEMENT:
This revision updates Section 1 (Chemical Product), Section 5 (fire
Fighting Measures), and Section 9 (Physical and Chemical Properties).
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity
RQ - Reportable Quantity PEL - Permissible Exposure Limit
C - Ceiling Limit CAS - Chemical Abstract Service Number
A1-5 - Appendix A Categories () - Change Has Been Proposed
NDA - No Data Available NA - Not Applicable
______________________________________________________________________
Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Toxicology
and Health Risk Assessment Unit, CRTC, P.O. Box 1627, Richmond, CA 94804
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______________________________________________________________________
The above information is based on the data of which we are aware and is
believed to be correct as of the date hereof. Since this information may
be applied under conditions beyond our control and with which we may be
unfamiliar and since data made available subsequent to the date hereof may
suggest modification of the information, we do not assume any responsibil-
ity for the results of its use. This information is furnished upon
condition that the person receiving it shall make his own determination
of the suitability of the material for his particular purpose.
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THIS IS THE LAST PAGE OF THIS MSDS
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